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High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

Frontiers in Energy doi: 10.1007/s11708-023-0892-6

Abstract: entropy materials (HEMs) have developed rapidly in the field of electrocatalytic water-electrolysis for oxygenevolution reaction (OER) and hydrogen evolution reaction (HER) due to their unique properties.stabilization of HEMs and their catalytic mechanisms as well as their application in support green hydrogen

Keywords: high-entropy     electrocatalysis     synthetic methods     water-electrolysis     hydrogen and oxygen evolutions    

Oxygen-deficient MoO/NiS heterostructure grown on nickel foam as efficient and durable self-supportedelectrocatalysts for hydrogen evolution reaction

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 4,   Pages 437-448 doi: 10.1007/s11705-022-2228-1

Abstract: High-performance and ultra-durable electrocatalysts are vital for hydrogen evolution reaction (HER) duringNi3S2 spheres comprising Ni3S2 nanoparticles inside and oxygen-deficientDensity functional theory calculations confirm that the existing oxygen vacancy and MoOx3S2 heterostructure are both beneficial to the reduced Gibbs free energy of hydrogen

Keywords: molybdenum oxides     oxygen vacancies     heterostructure     electrocatalysts     hydrogen evolution reaction    

Energy distribution between liquid hydrogen and liquid oxygen temperatures in a Stirling/pulse tube refrigerator

Frontiers in Energy 2023, Volume 17, Issue 4,   Pages 516-526 doi: 10.1007/s11708-022-0844-6

Abstract: In the present study, an SPR was designed and manufactured to work between the liquid hydrogen and liquidoxygen temperatures, which can be used to cool small-scale zero boil-off systems and space detectors

Keywords: Stirling/pulse tube refrigerator     displacer displacement     space application     phase shift     energy distribution    

nanosheets supported on N-doped carbon coated Ni foam as a highly active bifunctional electrocatalyst for hydrogenand oxygen evolution reactions

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 417-424 doi: 10.1007/s11705-018-1711-1

Abstract:

A highly active bi-functional electrocatalyst towards both hydrogen and oxygen evolution reactionsAs a bifunctional electrocatalyst, the NiCoP/NF@NC electrode needs overpotentials of 31.8 mV for hydrogenevolution reaction and 308.2 mV for oxygen evolution reaction to achieve the current density of 10 mA

Keywords: bimetallic phosphides     N-doped carbon     self-support     hydrogen evolution     oxygen evolution    

Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradationover an urchin-like oxygen-doped MoS/ZnInS composite

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1566-z

Abstract:

● An urchin-like OMS/ZIS composite was fabricated by a facile solvothermal method.

Keywords: Dual-functional photocatalysts     Oxygen-doped MoS2/ZnIn2S4     H2   

Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

Wenxin SHI, Chongwei CUI, Liye ZHAO, Shuili YU, Xia YUN

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 1,   Pages 107-111 doi: 10.1007/s11705-009-0154-0

Abstract: The removal of dissolved oxygen (DO) from water was studied experimentally in a Pd-resin base catalystreactor using purified hydrogen gas as a reducing agent.The effects of various operating conditions, such as hydrogen and water flow rates, height of the catalytic

Keywords: dissolved oxygen     palladium     catalytic reactor     hydrogen     resin    

Offshore wind power development and hydrogenoxygen) production industrial base construction in multi

Jin Chunpeng

Strategic Study of CAE 2015, Volume 17, Issue 3,   Pages 56-59

Abstract:

Wind energy is abundant (especially in coastal areas) that provides large space for wind power development. The application of large scale non-grid-connected wind power is one of the ways to multi-directional developing wind power. This paper analyzes the distribution and exploitation of wind resource in Jiangsu coastal areas,studies on industrial chain of “applying non-grid-connected wind power to high energy consumption industries” under the instruction of non-grid-connected wind power theory,and puts forward some suggestions for constructing industrial bases of non-grid-connected wind power in Jiangsu coastal areas.

Keywords: offshore wind power; multi energy cooperative supply; hydrogenoxygen) production; industrial base    

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient multifunctional electrocatalysts

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1487-1499 doi: 10.1007/s11705-021-2085-3

Abstract: Developing cost-effective electrocatalysts for oxygen reduction reaction (ORR), oxygen evolution reaction(OER) and hydrogen evolution reaction (HER) is vital in energy conversion and storage applications.

Keywords: MOF derivative     graphene     electrocatalyst     oxygen reduction reaction     oxygen evolution reaction     hydrogen    

Evaluation of the technoeconomic feasibility of electrochemical hydrogen peroxide production for decentralized

Yang Li, Yixin Zhang, Guangshen Xia, Juhong Zhan, Gang Yu, Yujue Wang

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 1, doi: 10.1007/s11783-020-1293-2

Abstract: This study evaluated the feasibility of electrochemical hydrogen peroxide (H2O2) production with gasblack-polytetrafluoroethylene GDEs were prepared and tested in a continuous flow electrochemical cell for H2O2 production from oxygenResults showed that because of the effective oxygen transfer in GDEs, the electrode maintained high apparentdecreased to ~70% in the following 4 days because water flooding of GDE pores considerably impeded oxygen

Keywords: Advanced oxidation process     Electro-peroxone     Gas diffusion electrode     Hydrogen peroxide     Oxygen reduction    

An overview and recent advances in electrocatalysts for direct seawater splitting

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1408-1426 doi: 10.1007/s11705-021-2102-6

Abstract: In comparison to pure water, seawater is widely accepted as an unlimited resource. The direct seawater splitting is economical and eco-friendly, but the key challenges in seawater, especially the chlorine-related competing reactions at the anode, seriously hamper its practical application. The development of earth-abundant electrocatalysts toward direct seawater splitting has emerged as a promising strategy. Highly efficient electrocatalysts with improved selectivity and stability are of significance in preventing the interference of side reactions and resisting various impurities. This review first discusses the macroscopic understanding of direct seawater electrolysis and then focuses on the strategies for rational design of electrocatalysts toward direct seawater splitting. The perspectives of improved electrocatalysts to solve emerging challenges and further development of direct seawater splitting are also provided.

Keywords: seawater splitting     electrocatalysts     oxygen evolution reaction     hydrogen evolution reaction     chlorine    

Speciation evolutions of target metals (Cd, Pb) influenced by chlorine and sulfur during sewage sludge

Jingde LUAN,Rundong LI,Zhihui ZHANG,Yanlong LI,Yun ZHAO

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 6,   Pages 871-876 doi: 10.1007/s11783-013-0621-1

Abstract: In sludge incineration, the thermal behavior of heavy metal is a growing concern. In this work, the combined analysis of metal partitioning behavior between vapor phase and condensed phase, speciation redistribution in condensed phase and the difference of metal species in binding energy was carried out to investigate the possible volatilization-condensation mechanism of heavy metals in high-temperature sludge incineration. It was found that there were two steps in metal volatilization. The initial volatilization of heavy metal originated from their exchangeable (EXC), carbonate bound (CAR) and iron–manganese bound (FM) fractions, which is primarily composed of simple substance, chlorides, oxides and sulfides. With the increase of chlorine and sulfur in sludge, the inner speciation redistribution of heavy metals occurred in condensed phase, which was an important factor affecting the potential volatility of heavy metals. A partial of metal species with complexed (COM) and residual (RES) fractions gradually decomposed into simple substance or ions, oxides and carbonates, which significantly strengthened the second volatility. In presence of chlorine, about 46% of Cd with the RES fraction disappeared when the volatility rate of Cd increased by 44.89%. Moreover, about 9% of Pb with COM fraction disappeared when there was an increase of nearly 10% in the volatilization rate. Thus, the second volatilization was mainly controlled by the decomposition of metal species with COM and RES fractions. By virtue of XRD analysis and the binding energy calculation, it was found that metal complex and silicates were inclined to decompose under high temperature due to poor thermo stability as compared with sulfates.

Keywords: sludge incineration     heavy metals     inner speciation redistribution     binding energy    

Preparation of ceria-zirconia solid solution with enhanced oxygen storage capacity and redox performance

Lijing MENG, Licheng LIU, Xuehong ZI, Hongxing DAI, Hong HE, Zhen ZHAO, Xinping WANG,

Frontiers of Environmental Science & Engineering 2010, Volume 4, Issue 2,   Pages 164-171 doi: 10.1007/s11783-010-0019-2

Abstract: ratios were prepared by the UAMR method and characterized by X-ray diffraction (XRD), N adsorption, hydrogenratio was lower than 1, in fabricating ceria-zirconia solid solutions with large BET surface area, high oxygen

Keywords: membrane reaction     ceria-zirconia     Ce/Zr molar ratio     solid solution     hydrogen temperature-programmed reduction    

Facile route to achieve MoSe-NiSe on nickel foam as efficient dual functional electrocatalysts for overall water splitting

Frontiers in Energy 2022, Volume 16, Issue 3,   Pages 483-491 doi: 10.1007/s11708-022-0813-0

Abstract: and the synergistic effect of MoSe2 and Ni3Se2 together enhance the hydrogenevolution reactions (HER), the oxygen evolution reactions (OER), and electrocatalytic total water splitting

Keywords: three-dimensional molybdenum nanomaterials     hydrogen evolution reaction     oxygen evolution reaction     overall    

Simultaneous CO

Jie ZHU,Wei WANG,Xiuning HUA,Zhou XIA,Zhou DENG

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 6,   Pages 1117-1129 doi: 10.1007/s11783-015-0812-z

Abstract: In this work, hydrogen generation with inherent CO capture in single packed bed reactor via this conceptTwo oxygen carriers, Fe O 60 wt.% and Fe O 55 wt.Then, in the long term tests using CO as fuel, it was proved that CuO addition improved hydrogen generationThe intensity of hydrogen production and the overall CO capture efficiency were in the range of 2000

Keywords: CO2 capture     chemical looping hydrogen generation     iron based oxygen carriers     single packed    

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reductionand oxygen evolution reaction: a density functional theory study

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 5,   Pages 570-580 doi: 10.1007/s11705-022-2247-y

Abstract: The oxygen reduction reaction and oxygen evolution reaction catalytic activities of heterometallic cluster-basedAmong all heterometallic clusters, Fe2Mn–Mn has a minimum overpotential of 0.35 V for oxygenreduction reaction, and Fe2Co–Co possesses the smallest overpotential of 0.32 V for oxygen

Keywords: bimetallic metal–organic frameworks     bifunctional electrocatalyst     density functional theory     oxygenreduction reaction     oxygen evolution reaction    

Title Author Date Type Operation

High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

Journal Article

Oxygen-deficient MoO/NiS heterostructure grown on nickel foam as efficient and durable self-supportedelectrocatalysts for hydrogen evolution reaction

Journal Article

Energy distribution between liquid hydrogen and liquid oxygen temperatures in a Stirling/pulse tube refrigerator

Journal Article

nanosheets supported on N-doped carbon coated Ni foam as a highly active bifunctional electrocatalyst for hydrogenand oxygen evolution reactions

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

Journal Article

Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradationover an urchin-like oxygen-doped MoS/ZnInS composite

Journal Article

Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

Wenxin SHI, Chongwei CUI, Liye ZHAO, Shuili YU, Xia YUN

Journal Article

Offshore wind power development and hydrogenoxygen) production industrial base construction in multi

Jin Chunpeng

Journal Article

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient multifunctional electrocatalysts

Journal Article

Evaluation of the technoeconomic feasibility of electrochemical hydrogen peroxide production for decentralized

Yang Li, Yixin Zhang, Guangshen Xia, Juhong Zhan, Gang Yu, Yujue Wang

Journal Article

An overview and recent advances in electrocatalysts for direct seawater splitting

Journal Article

Speciation evolutions of target metals (Cd, Pb) influenced by chlorine and sulfur during sewage sludge

Jingde LUAN,Rundong LI,Zhihui ZHANG,Yanlong LI,Yun ZHAO

Journal Article

Preparation of ceria-zirconia solid solution with enhanced oxygen storage capacity and redox performance

Lijing MENG, Licheng LIU, Xuehong ZI, Hongxing DAI, Hong HE, Zhen ZHAO, Xinping WANG,

Journal Article

Facile route to achieve MoSe-NiSe on nickel foam as efficient dual functional electrocatalysts for overall water splitting

Journal Article

Simultaneous CO

Jie ZHU,Wei WANG,Xiuning HUA,Zhou XIA,Zhou DENG

Journal Article

Heterometallic cluster-based organic frameworks as highly active electrocatalysts for oxygen reductionand oxygen evolution reaction: a density functional theory study

Journal Article